The proton–proton chain reaction is one of several fusion reactions by which stars convert hydrogen to helium, the primary alternative being the CNO cycle. The proton–proton chain dominates in stars the size of the Sun or smaller.
Overcoming electrostatic repulsion between two hydrogen nuclei requires a large amount of energy, and this reaction takes an average of more than 1010[citation needed] years to complete at the temperature of the Sun's core, because one of the protons has to beta decay via the weak interaction into a neutron during the brief moment of fusion. Because of the slow nature of this reaction the Sun is still shining; if it were faster, the Sun would have exhausted its hydrogen long ago.
In general, proton–proton fusion can occur only if the temperature (i.e. kinetic energy) of the protons is high enough to overcome their mutual Coulomb repulsion. The theory that proton–proton reactions were the basic principle by which the Sun and other stars burn was advocated by Arthur Stanley Eddington in the 1920s. At the time, the temperature of the Sun was considered too low to overcome the Coulomb barrier. After the development of quantum mechanics, it was discovered that tunneling of the wavefunctions of the protons through the repulsive barrier allows for fusion at a lower temperature than the classical prediction.